教育教学

李健辉研究生导师简介

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讲师，研究生导师，历任上市公司天赐材料（目前全球电解液产量与销量第一，龙头企业，股票代码002709）项目经理，邮箱：jianhuili@m.scnu.edu.cn，有十年电解液行业经验。

添加剂的设计、机理研究以及电解液配方的设计具有丰富经验

主持参与4项纵向科研项目，横向项目1项，以项目经理身份完成5项企业项目，发表SCI论文和核心期刊31篇，包含一作及通讯作者为17篇，论文包含angewandte等一区论文，授权发明专利8件，其中第一发明人7件。

以第一老师身份带领学生，获得校级、省级、国家级奖项9项。其中创业相关奖项7项。

成长经历：

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一作及通讯

  1.  J.H. Li, Z.Q. Fan, H.P. Ye, J.Y. Zheng, J.W. Qiu, H.X. He, P. Liu, M.X. He, H.D. Liu, N.D. Hoa, R.H. Zeng*, Novel Sulfur-based Electrolyte Additive for Constructing High-quality Sulfur-containing Electrode-electrolyte Interphase Films in Sodium-ion Batteries. Chem. Eng. J. 2024, 489, 151188.

  2. J.H. Li, Z.Q. Fan, J. Guo, J.Y. Zheng, W.T. Xie, Z. Fang, C.X. Yan, R.Z. Wang, H.R. Chen, H.X. He, A.A. Kasera, R.H. Zeng*, Insights into the Efficient Roles of Boron-containing Additives for Li-ion Batteries. Surfaces and Interfaces 2024, 48, 104309.

  3. Z.W. Zhang, Z.Q. Fan, J.H. Li*, H.X. He, H. Zhang, Z.X. Li, J.Y. Lin, X.Y. Zhang, J. Zhang, Research Progress on Electrolyte Additives for Sodium Ion Batteries. Sustainable Polymer & Energy 2024, 2, 10003.

  4. A. Zhou, Z. Li, D. Li, C.N. Cheng, X. Chen, Q.F. Wang, A.A. Kasera, J.H. Li*, Q. Hou, R.H. Zeng*, Triphenylamine-Supported Benzoquinone Polymer as High Performance Cathode for Lithium-Ion Batteries. ChemistrySelect 2024, 9, e202400538.

  5. J.W. Qiu, J. Guo, J.H. Li*, Y.P. Wu, Z.Q. Fan, H.P. Ye, Z. Fang, Z.W. Zhang, R.H. Zeng*, Insight into the Contribution of the Electrolyte Additive LiBF4 in High-Voltage LiCoO2||SiO/C Pouch Cells. ACS Appl. Mater. Interfaces 2023, 15, 56918-56929.

  6. Z.Q. Fan, X.Z. Zhou, J.W. Qiu, Z. Yang, C.X. Lei, Z.Q. Hao, J.H. Li*, L. Li, R.H. Zeng*, S.L. Chou*, Sulfur-Rich Additive-Induced Interphases Enable Highly Stable 4.6 V LiNi0.5Co0.2Mn0.3O2 || graphite Pouch Cells. Angew. Chem. Int. Ed., 2023, e202308888. 

  7. J. Guo#, J. H. Li#, Z. Q. Fan, J.W. Qiu, H.P. Ye, J.F. Liang, J.Y. Liang, R.H. Zeng*, Y.P. Cai*, Rationally Designing Cathode Interphase Chemistry via Electrolyte Additives for High-Voltage Batteries. ACS Appl. Energy Mater., 2023, 6, 2448-2461. （共同一作）

  8. J.H. Li, X.R. Yang, X.C. Guan, R.D. Guo, Y.X. Che, J.L. Lan, L.D. Xing*, M.Q. Xu, W.Z. Fan, W.S. Li*, Efficiently Suppressing Oxygen Evolution in High Voltage Graphite/NCM Pouch Cell with Tributyl Borate as Electrolyte Additive. Electrochim. Acta, 2020, 354, 13672-136730.

  9.  J.H. Li, Y.Q. Liao, W.Z. Fan, Z.F. Li, G.J. Li, Q.K. Zhang, L.D Xing*, M.Q. Xu, W.S. Li*, Significance of Electrolyte Additive Molecule Structure in Constructing Robust Interphases on High-Voltage Cathodes. ACS Appl. Energy Mater., 2020, 3, 3049-3058.

  10. J.H. Li, Z.S. Wang, Triethyl borate and Tripropyl Borate as Electrolyte Additives for 4.8 V High Voltage Layered Lithium-Rich Oxide Cathode with Enhanced Self-Discharge Suppression Performance: A Comparative Study. J. Power Sources, 2020, 450, 227648-227657.

  11. J.H. Li, L.D. Xing*, Z.S. Wang, W.Q. Tu, X.R. Yang, Y.L. Lin, Y.Q. Liao, M.Q. Xu, W.S. Li*, Insight into the Capacity Fading of Layered Lithium-Rich Oxides and Its Suppression via A Film-Forming Electrolyte Additive. RSC Adv., 2018, 8, 25794-25801

  12. J.H. Li, L.D. Xing*, J.W. Chen, H.B. Zhou, M.Q. Xu, W.S. Li*, Improving High Voltage Interfacial and Structural Stability of Layered Lithium-Rich Oxide Cathode by Using a Boracic Electrolyte Additive. J. Electrochem. Soc., 2016, 163 (10), A2258-A2264.

  13. J. H. Li, L.D. Xing*, L.P. Zhang, L. Yu, W.Z. Li, M.Q. Xu, W.S. Li*, Insight into Self-Discharge of Layered Lithium-Rich Oxide Cathode in Carbonate-Based Electrolytes with and without Additive. J. Power Sources, 2016, 324, 17-25.

  14. J.H. Li, L.P. Zhang, L. Yu, W.Z. Fan, Z.S. Wang, X.R. Yang, Y.L. Lin, L.D. Xing, M.Q. Xu, W.S. Li*, Understanding Interfacial Properties between Li-Rich Layered Oxide and Electrolyte Containing Triethyl Borate. J. Phys. Chem. C, 2016, 120, 26899-26907.

  15.  J. H. Li, L.D. Xing*, R.Q. Zhang, M. Chen, Z.S. Wang, M.Q. Xu, W.S. Li*, Tris(trimethylsilyl)borate as an Electrolyte Additive for Improving Interfacial Stability of High Voltage Layered Lithium-Rich Oxide Cathode/Carbonate-Based Electrolyte. J. Power Sources, 2015, 285, 360-366.

  16. 李健辉，余乐，范伟贞，赵经纬，硼酸三异丙酯对层状富锂正极材料的影响。电池，2018，48（3），154-158。

  17. 李健辉，邱景伟，范伟贞，赵经纬，ADN和HTCN添加剂用于钴酸锂/石墨电池。 电池，2023，53（1），48-51。

共同作者

  1. T.T. Li, J.L. Lin, L.D. Xing, Y.T. Zhong, H.F. Chai, W.D. Yang, J.H. Li, W.Z. Fan, J.W. Zhao, W. S. Li*, Insight into the Contribution of Nitriles as Electrolyte Additives to the Improved Performances of the LiCoO2 Cathode. J. Phys. Chem. Lett., 2022, 13, 8801-8807.

  2.  B. Li, Y.X. Shao, J.J. He, R.C. Chen, S.X. Huang, Z.L. Wu, J.H. Li, Z.S. Wang, G.C. Liu, Cyclability Improvement of High Voltage Lithium Cobalt Oxide/Graphite Battery by Use of Lithium Difluoro(oxalate)borate Electrolyte Additive. Electrochim. Acta, 2022, 426, 140783-140793.

  3.  R. D. Guo, Y. X. Che, G. Y. Lan, J. L. Lan, J. H. Li, L. D. Xing, K. Xu, W. Z. Fan, L. Yu, W. S. Li*, Tailoring Low-Temperature Performance of a Lithium-Ion Battery via Rational Designing Interphase on An Anode. ACS Appl. Mater. Interfaces, 2019, 11(41), 38285-38293.

  4.  J. L. Lan, Q. F. Zheng, H. B. Zhou, J. H. Li, L.D. Xing*, K. Xu, W.Z. Fan, L. Yu, W. S. Li*, Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive. ACS Appl. Mater. Interfaces, 2019, 11, 28841−28850.

  5. Z.H. Lin, J.H. Li, Q.M. Huang, K. Xu, W.Z. Fan, L. Yu, Q.B. Xia, W.S. Li*, Insights into the Interfacial Instability between Carbon-Coated SiO Anode and Electrolyte in Lithium-Ion Batteries. J. Phys. Chem. C, 2019,123, 12902-12909.

  6. Y.L. Lin, J.H. Li, L.D. Xing, Y.H. Liao, M.Q. Xu, X. Liu, W.S. Li*, Optimal Concentration of Electrolyte Additive for Cyclic Stability Improvement of High Voltage Cathode of Lithium-Ion Battery. Ionics, 2018, 24, 661-670.

  7. X.R. Yang, J.H. Li, L.D. Xing, Y.H. Liao, M.Q. Xu, Q.M. Huang, W.S. Li*, Stabilizing Lithium Manganese Oxide/Organic Carbonate Electrolyte Interface with A Simple Boron-Containing Additive. Electrochim. Acta, 2017, 227, 24-32.

  8. W.Q. Tu, P. Xia, J. H. Li, L. Z. Zeng, M.Q. Xu, L.D. Xing, L. P. Zhang, L. Yu, W.Z. Li, W.S. Li*, Terthiophene as Electrolyte Additive for Stabilizing Lithium Nickel Manganese Oxide Cathode for High Energy Density Lithium-Ion Batteries. Electrochim. Acta, 2016, 208, 251-259.

  9. Z.S. Wang, L.D. Xing, J. H. Li, M. Q. Xu*, W.S. Li*, Triethylborate as An Electrolyte Additive for High Voltage Layered Lithium Nickel Cobalt Manganese Oxide Cathode of Lithium Ion Battery. J. Power Sources, 2016, 307, 587-592.

  10. Z.S. Wang, L.D. Xing, J.H. Li, B. Li, M.Q. Xu, Y.H. Liao, W.S. Li*, Trimethyl Borate as An Electrolyte Additive for High Potential Layered Cathode with Concurrent Improvement of Rate Capability and Cyclic Stability. Electrochim. Acta, 2015, 184, 40-46.

  11. Z.S. Wang, M.M. Rao, J.H. Li, C. C. Ye, Z. D. Liu, Q. S. Xu, X. J. Jin, R. A. Du, Q.M. Xie, W. Luo, W.S. Li*, Y.C. Qiu, Understanding the Mechanism of Cycling Degradation and Novel Strategy to Stabilize the Cycling Performance of Graphite/LiCoO2 Battery at High Voltage. J Electroanal Chem., 2019, 851, 113411-113421.

  12. Z.S. Wang, Z.M. Xu, X.J. Jin, J.H. Li, Q.S. Xu, Y.N. Chong, C.C. Ye, W.S. Li*, D.Q. Ye, Y.Y. Lu, Y.C. Qiu, Dendrite-Free and Air-Stable Lithium Metal Batteries Enabled by Electroless Plating with Aluminum Fluoride. J. Mater. Chem. A, 2020, 8, 9218-9227.

  13. Y.T. Wang, M.Z. Liu, J.S. Zhou, S.R. Chen, J.H. Li, J. Liu, Y. Sun, Z.C. Shi, DFT Study on the Oxidation Mechanism of Common Cyclic Carbonates in the Presence of BF4-Anions. J. Phys. Chem. A 2023, 127, 3958-3965

  14. X.R. Yang, Y.X. Huang, J.H. Li, W.L. Huang, W. Yang, C.Q. Wu, S.J. Tang, F.C. Ren, Z.L. Gong, N.G. Zhou, Y. Yang, Understanding of Working Mechanism of Lithium Difluoro(oxalato)borate in Li||NCM85 Battery with Enhanced Cyclic Stability. Energy Mater 2023, 3,300029.

专利

  1. 李健辉、范伟贞、王漪、信勇、赵经纬，一种含四氰基的腈醚类电解液添加剂和电解液及锂离子电池，ZL112768772B。

  2. 李健辉、陈锦绣、曾荣华、邱景伟、范自强、叶海平、方洲、张芷雯，钠离子电池电解液、钠离子电池和提高钠离子电池性能的方法，ZL116779969B。

  3. 李健辉、范伟贞、赵经纬，一种锂二次电池电解液、锂二次电池，ZL110247119B。

  4. 李健辉、范伟贞、谢添、余乐、赵经纬、郭娟， 一种新型锂二次电池电解液和一种锂二次电池，ZL108539273B。

  5. 李健辉、范伟贞、信勇、赵经纬，一种含氟磺酸酯电解液添加剂和含有该添加剂的电解液及锂离子电池，ZL112054241B。

  6. 李健辉、范伟贞、王漪、信勇、赵经纬，一种电解液添加剂、电解液、锂二次电池，ZL113745660B。

  7. 李健辉、范伟贞、赵经纬、周萌，半导体加工用粘合剂及提高半导体加工性能的方法，ZL 115521743B。

  8. 曾荣华、李健辉，一种锂盐电解液添加剂和含有该添加剂的电解液及锂离子电池，ZL112186246B。

纵向项目（主持或参与）

  1. 国家自然科学基金（项目编号：21972049）：钠离子电池硬碳负极/碳酸酯基电解液界面性质的研究，60万；

  2. 广东省基础与应用基础研究基金（项目编号：2021A1515010141）：高安全凝胶聚合物隔膜稳定高容量金属锂负极的机理研究，10万。

  3. 广东省基础与应用基础研究基金（项目编号：2023A1515011659）：多位点共掺杂调控锰基层状氧化物P2-NaxMnO2正极阴离子氧化还原活性，10万。

  4. 华南师范大学青年教师科研培育基金（项目编号：671866）：多功能硼酸酯添加剂的设计和性能及机理研究，3万。